The UNECE Convention on Long Range Transboundary Air Pollutants operates a number of measurement and monitoring programmes, including EMEP – the Co-operative Programme for Monitoring and Evaluation of the Long-range Transmission of Air Pollutants in Europe.

The United Kingdom contribution to the EMEP monitoring strategy is based on the creation of two Level II ‘supersites’, one in the north of the UK and one in the south, at which additional measurements are made to qualify as an EMEP Level III site. Data from these sites at hourly or daily frequency are supplemented by long-term integrating measurements from existing Defra-funded monitoring networks across the UK. The northern site is identified as Auchencorth Moss in eastern Scotland (UK OS grid reference NT220562) which has been used by the Centre for Ecology & Hydrology for several years as an intensive monitoring site for trace gas and particle concentrations and fluxes. The site is based in an area of upland deep peat, with heather and grass cover, and has an extensive fetch to the south-west. The southern site is identified as Harwell, in Oxfordshire, operated by AEA Technology over many years for sampling trace gases and aerosols.

Auchencorth 'Super Site'

a photo of the Auchencorth field site

Auchencorth Super Site (UK OS grid reference NT220562)

 
a photo of the wet deposition collector
 
Daily wet-only deposition collector


 

Harwell 'Super Site'

a photo of the MARGA

MARGA (Monitor for AeRosols and Gases in Air) at Harwell

 
a photo of the ANNOx
 
ANNOx at Harwell


 

Summary of Measurements at the EMEP Supersites (with links to the responsible monitoring networks)

MeasurementMethodEMEP LevelAuchencorthHarwell
Water-soluble gases and particles at PM2.5 and PM10MARGA1,2,3UKEAPUKEAP
Black carbon PM2.5Aethalometer2Black CarbonBlack Carbon
NO/NO2Photolytic converter2UKEAPUKEAP
Meteorology (wind speed, dir’n., temp., RH, precip’n.)Automated met station1CEHUKEAP
OzoneUV photometer1AURNAURN
PM2.5 and PM10 mass (daily)Filter (gravimetric)1AURNAURN
PM2.5 and PM10 mass (hourly)TEOM/FDMS1AURNAURN
PAH (vapour and particle)Digitel hi-vol2PAHPAH
PAH (precipitation)Bulk sampler2PAHPAH
TOMPS (air)Hi-vol2TOMPSTOMPS
Hydrocarbons (C2 – C8)Online GC-FID2HydrocarbonsHydrocarbons
Particle size and numberSMPS2CEH/ACTRISParticles
Mercury (elemental) in airCVAF12Heavy metalsHeavy metals
Mercury (speciated) in airCVAF 3Heavy metalsNot measured
Mercury (precipitation)CVAF2Heavy metalsHeavy metals
Heavy metals PM10 (air)ICP-MS2Heavy metalsHeavy metals
Heavy metals (precip’n)ICP-MS1Heavy metalsHeavy metals

Ions in precipitation 

Daily wet-only collector:

I.C., pH, conductance1UKEAPUKEAP

Ions in bulk precipitation 

Fortnightly bulk measurement

I.C., pH, conductance1UKEAPUKEAP
Acid gases and aerosol (monthly)Denuders+filters1,2UKEAPUKEAP
Ozone, NOx, SO2 fluxesAutomated analyzers3PDPN/A
Trace gas fluxesCoTAG3PDPN/A
ECOC (weekly)Filter3ParticlesParticles